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Electron Mobility
In physics,
electron mobility (or simply,
mobility), is a quantity relating the drift velocity of
electrons to the applied
electric field across a material, according to the formula:
\,v_d = \mu E
where
\, v_d is the drift velocity
\, E is the applied electric field
\, \mu is the mobility
In
semiconductors,
mobility can also apply to
Electron hole as well as electrons.
Conceptual overview
In a solid, electrons (and in the case of
semiconductors,
electron hole) will
Brownian motion in the absence of an applied electric field. Therefore, if one averages the movement over time there will be no overall motion of charge carriers in any particular direction. However upon applying an electric field, electrons will be accelerated in an opposite direction to the electric field. The summation of the time between acceleration of electrons due to electric field and deceleration of electrons due to collisions and lattice scattering events (caused by
phonons, crystal defects, impurities, etc.) over the mean free path between scattering events results in the electrons having an average drift velocity. This net electron motion must be orders of magnitude less than the normally occurring random motion, otherwise the mobility equation is not valid (i.e., typical drift speeds in copper being of the order of 10-4 m·s−1 compared to the speed of random electron motion of 105 m·s−1).
In a semiconductor the two charge carriers, electron and Electron hole, will typically have different drift velocities for the same electric field.
In a Plasma (physics) there is analogous behavior with
ions and free electrons.
In a
vacuum, electrons will accelerate non-stop in an electric field according to Newton's second
Newton's laws of motion. This is known as "ballistic transport". Thus electron mobility is undefined for electronic movement in a vacuum.
In a solid, if the electrons must move only a very short distance (distance comparable with the Brownian motion), quasi-
ballistic transport is possible.
In
SI units, mobility is normally measured in metre2/(volt·second). Since mobility is usually a strong function of material impurities and temperature, and is determined empirically, mobility values are typically presented in table or chart form. Mobility is also different for electrons and holes in a
semiconductor.
An approximation of the mobility function can be written as a combination of influences from lattice vibrations (
phonons) and from impurities by the Matthiessen's Rule:
\mu = \frac{1}{\frac{1}{\mu_{\rm lattice-->+\frac{1}{\mu_{\rm impurities-->}.
(Note: Matthiessen's rule originated from Augustus MatthiessenA. Matthiessen, Rep. Brit. Ass. 32, 144 (1862)A. Matthiessen, Progg. Anallen, 122, 47 (1864), who studied electrical conduction in metals. In his days, people might not even know the existence of semiconductors, as Augustus Matthiessen (1831-1870) lived in the days before superconductivity was discovered by
Heike Kamerlingh Onnes in about 1911.)
Mobility in gas phase
Mobility is defined for any species in the gas phase, encountered mostly in
Plasma (physics) physics and is defined as:
\mu = \frac{q}{m\, \nu_m}
where
\, q is the charge of the species,
\, \nu_m is the momentum transfer collision frequency, and
\, m is the mass.
Mobility is related to the species'
diffusion coefficient \, D through an exact (thermodynamically required) equation known as the Einstein relation:
\mu = \frac{q}{k\, T}D,
where
\, k is the
Boltzmann constant,
\, T is the gas temperature, and
\, D is a measured quantity that can be estimated. If one defines the mean free path in terms of
momentum transfer, then one gets:
D = \frac{\pi}{8}\lambda^2 \nu_m.
But both the
momentum transfer mean free path and the
momentum transfer collision frequency are difficult to calculate. Many other mean free paths can be defined. In the gas phase, \, \lambda is often defined as the diffusional mean free path, by assuming a simple approximate relation is exact:
D = \frac{1}{2}\lambda \vee.
When \, v is the
root mean square speed of the gas molecules:
v = \sqrt {{3\, k\, T}\over{m-->
where
\, m is the mass of the diffusing species. This approximate equation becomes exact when used to define the diffusional mean free path.
Mobility at the silicon dioxide / silicon interface of MOSFET transistors
For n-channel or p-channel
MOSFETs, the electron or hole mobility at the
silicon dioxide / silicon interface has a very strong effect on the speed of the device. In 1997, Professor Mark Lundstrom of
Purdue University pointed out for Nanoelectronics, quasi-
ballistic transport is possible and maximum charge carrier speed is controlled by mobility (instead of by
velocity saturation according to conventional theory)M.S. Lundstrom, IEEE Electron Device Letters, 18, 361 (1997).. Increasing the mobility of MOSFETs can have a profound benefit to
digital electronics, thus all major digital semiconductor manufacturers have been exploring methods to increase mobility at the silicon dioxide / silicon interface of MOS transistors. One important approach is known as strain engineering.
Usually, three Scattering theory are present at the silicon dioxide / silicon interface of MOS transistors:
Coulombic scattering at a gate voltage slightly above the threshold voltage.
Phonon scattering at a higher gate voltage.
Surface roughness scattering at a higher gate voltage.
Recently, scientists have been studying the possibility of "remote Coulombic scattering", which is also known as "remote charge scattering"J. Koga, T. Ishihara and S. Takagi, IEEE Electron Device Letters, 24, 354, (2003).. Remote charge scattering can come from two sources:
Remote charge scattering due to ionized impurities in the Polycrystalline silicon gate.
Remote charge scattering due to trapped charge in the high-k dielectric.
In 2005, W.S. Lau pointed out as Lau's hypothesis that "remote Coulombic scattering" is only important in the
subthreshold region and in the region slightly above threshold.C. W. Eng, W. S. Lau, D. Vigar, S. S. Tan and L. Chan, Applied Physics Letters, 87, article number 153510 (2005)..
Examples
Typical electron mobility for
Si at room temperature (300 K) is 0.92 m2/(V·s)
References
External links
- semiconductor glossary entry for electron mobility
- Bart Van Zeghbroeck's Online Book, Principles of Semiconductor Devices
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